Thermodynamics of the Reactions at Solid/Liquid Interfaces

Kallay, Nikola and Preočanin, Tajana and Kovačević, Davor and Lützenkirchen, Johannes and Villalobos, Mario (2011) Thermodynamics of the Reactions at Solid/Liquid Interfaces. Croatica Chemica Acta, 84 (1). pp. 1-10. ISSN 0011-1643

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The present review discusses the state of the art of the thermodynamic treatment for variable charge at solid/liquid interfaces. The most important equations are given for the case of generic surface sites. This can easily be extended to the more general case for multiple surface sites. Detailed aspects involving thermodynamic standard states of simple and multidentate surface complexes are addressed, and relationships between the commonly-used empirical adsorption isotherms and the Surface Complexation Model are presented.

Item Type: Article
Keywords: surface charge, solid/liquid interface, surface complexation model
Date: 2011
Subjects: NATURAL SCIENCES > Chemistry
Divisions: Faculty of Science > Department of Chemistry
Publisher: Hrvatsko kemijsko društvo
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Depositing User: Branka Maravic
Date Deposited: 08 May 2014 12:42
Last Modified: 08 May 2014 12:42

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