Chlorocarbocations and Concept of the Electron Donating Ability

Vančik, Hrvoj (2000) Chlorocarbocations and Concept of the Electron Donating Ability. Croatica Chemica Acta, 73 (2). pp. 595-604. ISSN 0011-1643

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Stabilization effects and the electron donating ability of α-substituents in carbocations are considered as different chemical concepts. The discussion is based on quantum chemical and spectroscopic investigations of methyl- and chlorosubstituted carbocations. It has been demonstrated that the methyl group affords a better stabilizing effect but that chlorine acts as a better electron donor. These effects are studied in classical α-chlorocarbocations as well as in chloroallyl cations and aromatic systems.

Item Type: Article
Keywords: chlorocarbocations; methylsubstituted carbocations; electron donating ability
Date: 2000
Subjects: NATURAL SCIENCES > Chemistry
Divisions: Faculty of Science > Department of Chemistry
Publisher: Hrvatsko kemijsko društvo
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Depositing User: mag. bibl. Ana Šafran
Date Deposited: 26 May 2014 09:42
Last Modified: 26 May 2014 09:42

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