Synthesis and structure of halogen bonded cocrystals of an o-hydroxy imine

Nogalo, Ivana (2016) Synthesis and structure of halogen bonded cocrystals of an o-hydroxy imine. Diploma thesis, Faculty of Science > Department of Chemistry.

[img]
Preview
PDF
Language: Croatian

Download (6MB) | Preview

Abstract

Within this master thesis an imine was prepared through condensation of o-vanillin and 4-aminobenzonitrile. The possibility of cocrystallization of the selected imine and two halogen bond donors (1,2- and 1,4-diiodotetrafluorobenzene) was investigated by means of mechanochemical synthesis, solution based synthesis and accelerated ageing. The cocrystals were described by powder X-ray diffraction, thermogravimetry and differential scanning calorimetry. The crystal and molecular structures of two prepared compounds were explored by single crystal X-ray diffraction, and correlated with thermal properties.

Item Type: Thesis (Diploma thesis)
Keywords: halogen bond, imine, cocrystals, mechanochemical synthesis
Supervisor: Cinčić, Dominik
Date: 2016
Number of Pages: 77
Subjects: NATURAL SCIENCES > Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Branka Maravic
Date Deposited: 20 Oct 2016 10:23
Last Modified: 20 Oct 2016 10:23
URI: http://digre.pmf.unizg.hr/id/eprint/5191

Actions (login required)

View Item View Item